Ytterbium(III) oxide

Ytterbium(III) oxide is the chemical compound with the formula Yb2O3. It is one of the more commonly encountered compounds of ytterbium. It has the "rare-earth C-type sesquioxide" structure which is related to the fluorite structure with one quarter of the anions removed, leading to ytterbium atoms in two different six coordinate (non-octahedral) environments.[2]

Ytterbium(III) oxide
Names
IUPAC name
Ytterbium(III) oxide.
Other names
Ytterbia
diytterbium trioxide
ytterbium sesquioxide
Identifiers
CAS Number
ECHA InfoCard 100.013.850
UNII
CompTox Dashboard (EPA)
Properties
Chemical formula
Yb2O3
Molar mass 394.08 g/mol
Appearance White solid.
Density 9.17 g/cm3, solid.
Melting point 2,355 °C (4,271 °F; 2,628 K)
Boiling point 4,070 °C (7,360 °F; 4,340 K)
Solubility in water
Insoluble
Structure
Crystal structure
Cubic
Coordination geometry
Octahedral
Thermochemistry
Std molar
entropy (So298)
133.05 J/mol·K [1]
Std enthalpy of
formation fH298)
-1814.600 kJ/mol [1]
Gibbs free energy (ΔfG˚)
-1726.844 kJ/mol [1]
Hazards
EU classification (DSD) (outdated)
None listed.
R-phrases (outdated) None listed.
S-phrases (outdated) None listed.
NFPA 704 (fire diamond)
0
1
1
Flash point Non-flammable.
Related compounds
Other anions
Ytterbium(III) sulfide, Ytterbium(III) chloride
Other cations
Thulium(III) oxide
Lutetium(III) oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Uses

  • Colorant for glasses and enamels
  • Dopant for garnet crystals in lasers
  • Optical fibers

See also

  • Active laser medium

References

  1. R. Robie, B. Hemingway, and J. Fisher, “Thermodynamic Properties of Minerals and Related Substances at 298.15K and 1bar Pressure and at Higher Temperatures,” US Geol. Surv., vol. 1452, 1978.
  2. Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN 0-19-855370-6
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