Indium arsenide

Indium arsenide
Names
IUPAC name
Indium(III) arsenide
Other names
Indium monoarsenide
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.742
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/As.In checkY
    Key: RPQDHPTXJYYUPQ-UHFFFAOYSA-N checkY
  • InChI=1/As.In/rAsIn/c1-2
    Key: RPQDHPTXJYYUPQ-FVESRWMKAB
SMILES
  • [In+3].[As-3]
  • [In]#[As]
Properties
Chemical formula
InAs
Molar mass 189.740 g/mol
Density 5.67 g/cm3[1]
Melting point 942 °C (1,728 °F; 1,215 K)942[1]
Band gap 0.354 eV (300 K)
Electron mobility 40000 cm2/(V*s)
Thermal conductivity 0.27 W/(cm*K) (300 K)
Refractive index (nD)
4[2]
Structure
Crystal structure
Zinc blende
Lattice constant
a = 6.0583 Å
Thermochemistry[3]
Heat capacity (C)
47.8 J·mol−1·K−1
Std molar
entropy (S298)
75.7 J·mol−1·K−1
Std enthalpy of
formation fH298)
−58.6 kJ·mol−1
Gibbs free energy fG)
−53.6 kJ·mol−1
Hazards
GHS labelling:
Pictograms
GHS06: ToxicGHS08: Health hazard[4]
Signal word
Danger[4]
Hazard statements
H301, H331[4]
Precautionary statements
P261, P301+P310, P304+P340, P311, P405, P501[4]
NFPA 704 (fire diamond)
NFPA 704 four-colored diamond
4
0
0
Safety data sheet (SDS) External SDS
Related compounds
Other anions
Indium nitride
Indium phosphide
Indium antimonide
Other cations
Gallium arsenide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Indium arsenide, InAs, or indium monoarsenide, is a narrow-bandgap semiconductor composed of indium and arsenic. It has the appearance of grey cubic crystals with a melting point of 942 °C.[5]

Indium arsenide is similar in properties to gallium arsenide and is a direct bandgap material, with a bandgap of 0.35 eV at room temperature.

Indium arsenide is used for the construction of infrared detectors, for the wavelength range of 1.0–3.8 μm. The detectors are usually photovoltaic photodiodes. Cryogenically cooled detectors have lower noise, but InAs detectors can be used in higher-power applications at room temperature as well. Indium arsenide is also used for making diode lasers.

InAs is well known for its high electron mobility and narrow energy bandgap. It is widely used as a terahertz radiation source as it is a strong photo-Dember emitter.

Quantum dots can be formed in a monolayer of indium arsenide on indium phosphide or gallium arsenide. The mismatches of lattice constants of the materials create tensions in the surface layer, which in turn leads to the formation of the quantum dots.[6] Quantum dots can also be formed in indium gallium arsenide, as indium arsenide dots sitting in the gallium arsenide matrix.

References

  1. ^ a b Haynes, p. 4.66
  2. ^ Haynes, pp. 12.157
  3. ^ Haynes, p. 5.22
  4. ^ a b c d "Indium Arsenide". American Elements. Retrieved October 12, 2018.
  5. ^ "Thermal properties of Indium Arsenide (InAs)". Archived from the original on 2012-04-14. Retrieved 2011-11-22.
  6. ^ "oe magazine - eye on technology". Archived from the original on 2006-10-18. Retrieved 2011-11-22.

Cited sources

  • Haynes, William M., ed. (2016). CRC Handbook of Chemistry and Physics (97th ed.). CRC Press. ISBN 9781498754293.