Calcium chromate
Calcium chromate (CaCrO4) is a bright yellow solid. It normally occurs as the dihydrate, although the very rarely natural (mineral) form, known as chromatite, is anhydrous.[1] Very toxic.
![]() Calcium chromate | |
![]() Calcium chromate dihydrate | |
Names | |
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IUPAC name
Calcium dioxido-dioxo-chromium | |
Other names
Calcium chromate (VI) Calcium monochromate Calcium Chrome Yellow C. I. Pigment Yellow 33 Gelbin Yellow Ultramarine | |
Identifiers | |
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ChemSpider | |
ECHA InfoCard | 100.033.955 |
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Properties | |
Chemical formula |
CaCrO4 |
Molar mass | 156.072 g/mol |
Appearance | bright yellow powder |
Density | 3.12 g/cm3 |
Melting point | 2,710 °C (4,910 °F; 2,980 K) |
Solubility in water |
anhydrous 4.5 g/100 mL (0 °C) 2.25 g/100 mL (20 °C) dihydrate 16.3 g/100mL (20 °C) 18.2 g/100mL (40 °C) |
Solubility | soluble in acid practically insoluble in alcohol |
Structure | |
Crystal structure |
monoclinic |
Related compounds | |
Other anions |
calcium dichromate |
Other cations |
Beryllium chromate Magnesium chromate Strontium chromate Barium chromate Radium chromate |
Hazards | |
Main hazards | highly toxic, carcinogen, mutagen |
NFPA 704 (fire diamond) | ![]()
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1 OX |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Infobox references | |
Properties
Calcium chromate loses water at 200 °C. It reacts with organic matter or reducing agents to form chromium(III). The solid will react explosively with hydrazine. If mixed with boron and ignited, calcium chromate will burn violently.[2]
Uses
It is used as a pigment, a corrosion inhibitor, and in electroplating, photochemical processing, and industrial waste treatment.
References
- http://www.mindat.org
- Occupational Safety And Health Guideline For Calcium Chromate Archived August 8, 2007, at the Wayback Machine