Cobalt(II) oxalate
Cobalt(II) oxalate is the inorganic compound with the formula of CoC2O4. Like other simple inorganic oxalates, it is a coordination polymer. The oxalate ligands bridge of Co(OH2)2 centres. Each cobalt adopts octahedral coordination geometry.[1]
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ECHA InfoCard | 100.011.281 |
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Properties | |
Chemical formula |
CoC2O4 |
Molar mass | 146.9522 g/mol |
Appearance | gray/pink powder |
Odor | odorless |
Density | 3.01 g/cm3 |
Melting point | 250 °C (482 °F; 523 K) (decomposes) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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It is used in the preparation of cobalt catalysts, and cobalt metal powder for powder-metallurgical applications. It is made in process of recycling lithium-ion batteries, where the cobalt is obtained from cathode material (LiCoO2) by leaching with sulfuric acid and then precipitated with ammonium oxalate.
References
- Bacsa, J.; Eve, D.; Dunbar, K. R. (2005). "catena-Poly[[diaquacobalt(II)]-μ-oxalato]". Acta Crystallogr. C. 61: m58–m60. doi:10.1107/S0108270104030409.