Palladium(II) bromide
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CAS Number
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3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.033.248 |
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
Chemical formula
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Br2Pd |
| Molar mass | 266.228 g/mol |
| Hazards | |
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Pictograms
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Signal word
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Warning |
Hazard statements
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H315, H319, H335 |
Precautionary statements
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P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, P501 |
| Related compounds | |
Other anions
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Palladium(II) fluoride Palladium(II) chloride Palladium(II) iodide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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Palladium(II) bromide is an inorganic compound of palladium and bromine with the chemical formula PdBr2. It is a commercially available, although less common than palladium(II) chloride, the usual entry point to palladium complexes. It is a diamagnetic solid.
Structure
As confirmed by X-ray crystallography, PdBr2 is a coordination polymer.[2] It crystallises in the P21/c space group and the structure consists of wavy ribbons of edge-sharing PdBr4 coordination squares.[3]
Reactions
Palladium(II) bromide is insoluble in water but dissolves when heated in acetonitrile to give monomeric acetonitrile adducts:[4]
- PdBr2 + 2 MeCN → PdBr2(MeCN)2
PdBr2 exhibits many of the properties of palladium chloride and palladium acetate, giving catalysts active for carbonylations and cross-coupling reactions.[5]
References
- ^ PubChem. "Palladium bromide (PdBr2)". pubchem.ncbi.nlm.nih.gov. Retrieved 2026-02-27.
- ^ K. Brodersen, G. Thiele, H. Gaedcke (1966). "Die Konstitution des Palladium(II)-bromids". Z. Anorg. Allg. Chem. 348 (3–4): 162–167. doi:10.1002/zaac.19663480307.
{{cite journal}}: CS1 maint: multiple names: authors list (link) - ^ "Information card for entry 1534319". Crystallography Open Database. 1966. Retrieved 2020-05-03.
- ^ O. A. Zalevskaya, E. G. Vorob'eva1, I. A. Dvornikova and A. V. Kuchin (2008). "Palladium Complexes Based on Optically Active Terpene Derivatives of Ethylenediamine". Russian Journal of Coordination Chemistry. 34 (11): 855–857. doi:10.1134/S1070328408110110. S2CID 95529734.
{{cite journal}}: CS1 maint: multiple names: authors list (link) CS1 maint: numeric names: authors list (link) - ^ Mahoney, Stuart J.; Fillion, Eric (2013). "Palladium(II) Bromide". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rn01617. ISBN 978-0471936237.